Constructing Porous Carbon Electrocatalysts from Cobalt Complex-Decorated Micelles of Mesoporous Silica for Oxygen Reduction/Evolution Reaction

The construction of a porous carbon structure with a high specific surface area is conducive to enhanced electrocatalytic activity due to the accessibility of active sites and improvement of the mass transfer. Herein, we explored the possibility of using micelles of mesoporous silica (MCM-48) as the carbon source to generate porous carbon under the confinement of MCM-48 channels. The complexes formed by Co2+ and 4,4′-bipyridine were in situ...