Cobalt-Catalyzed Cross-Dehydrogenative C(sp2 )−C(sp3 ) Coupling of Oxazole/Thiazole with Ether or Cycloalkane
Abstract
Direct C5-alkylation of oxazole/thiazole with ether or cycloalkane has been achieved through a cobalt-catalyzed cross-dehydrogenative coupling (CDC) process in moderate to good yields. This transformation represents the first C(sp2)−C(sp3) cross-coupling at the C5-position of the oxazole/thiazole via double C−H bond cleavages. Various functional groups on oxazole/thiazole substrates, as well as water and air, are well-tolerated with this concise...
Paper Details
Title
Cobalt-Catalyzed Cross-Dehydrogenative C(sp2 )−C(sp3 ) Coupling of Oxazole/Thiazole with Ether or Cycloalkane
Published Date
Oct 13, 2017
Journal
Volume
12
Issue
21
Pages
2799 - 2803
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