An Operative Electrostatic Slipping Mechanism along Macrocycle Flexibility Accelerates Guest Sliding during pseudo ‐Rotaxane Formation

Volume: 11, Issue: 6
Published: Jun 1, 2022
Abstract
A pseudo-rotaxane is a host-guest complex composed of a linear molecule encircled by a macrocyclic ring. These complexes can be assembled by sliding the host over the guest terminal groups. If there is a close match between the molecular volume of the flanking groups on the guest and the cavity size of the macrocycle, the slipping might occur slowly or even become completely hindered. We have previously shown that it is possible to overcome the...
Paper Details
Title
An Operative Electrostatic Slipping Mechanism along Macrocycle Flexibility Accelerates Guest Sliding during pseudo ‐Rotaxane Formation
DOI
Published Date
Jun 1, 2022
Journal
Volume
11
Issue
6
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