Stimuli‐Responsive Aggregation of High Molar Mass Poly(N,N‐Diethylacrylamide)‐b‐Poly(4‐Acryloylmorpholine) in Tetrahydrofuran

The self-assembly of block copolymers constitutes a timely research area in polymer science with implications for applications like sensing or drug-delivery. Here, the unprecedented aggregation behavior of high molar mass block copolymer poly(N,N-diethylacrylamide)-b-poly(4-acryloylmorpholine) (PDEA-b-PAM) (Mn >400 kg mol-1 ) in organic solvent tetrahydrofuran (THF) is investigated. To elucidate the aggregation, dynamic light scattering,...