Recent Developments in the Chemistry of Pn(I) (Pn=N, P, As, Sb, Bi) Cations
Abstract
The Group 15 Pn(I) cations (Pn=N, P, As, Sb and Bi), which are isoelectronic with the donor-stabilized carbones, have emerged recently. Despite the presence of two lone pair of electrons, the Pn(I) cations are weakly nucleophilic due to their inherent positive charge. Strongly electron-donating supporting ligands including zwitterionic forms have been used to enhance their Lewis basicity. Furthermore, the chelating effect of cyclic ligand...
Paper Details
Title
Recent Developments in the Chemistry of Pn(I) (Pn=N, P, As, Sb, Bi) Cations
Published Date
Dec 2, 2021
Journal
Volume
17
Issue
1
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