A Stereoselective Synthesis of Fused Carbocycles with a <i>cis</i>-1,2-Diol Moiety by Desymmetrization: SmI<sub>2</sub>-Mediated Pinacol Coupling of <i>meso</i>-Cyclic 1,3-Diones
Abstract
Samarium diiodide (SmI2)-mediated desymmetrization of a meso-cyclic 1,3-dione pinacol coupling is described. The reaction proceeds with high stereoselectivity to provide fused carbocyclic compounds with three contiguous stereogenic centers featuring an all-carbon quaternary center and a cis-1,2-diol...
Paper Details
Title
A Stereoselective Synthesis of Fused Carbocycles with a <i>cis</i>-1,2-Diol Moiety by Desymmetrization: SmI<sub>2</sub>-Mediated Pinacol Coupling of <i>meso</i>-Cyclic 1,3-Diones
Published Date
Jan 1, 2022
Volume
70
Issue
1
Pages
89 - 93
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