A disubstituted-norbornene-based comonomer strategy to address polar monomer problem

The transition-metal-catalyzed copolymerization of olefins with polar comonomers is a direct strategy to access polar-functionalized polyolefins in an economical manner. Due to the intrinsic poisoning effect of polar groups towards Lewis acidic metal centers and the drastic reactivity differences of polar comonomers versus non-polar olefins , it is challenging to develop catalysts that provide the desired polymer molecular weight , comonomer...