emission

vegf

luminescent

silver complexes

kirchhoff

window

coordination_56827

complexes_56769

halides

parenting stress

food delivery

flow heat transfer

complexes_111710

complexes_5671

sub cu

pathogenic bacteria

lymphoid tissue

french studies volume_94336

Inorganic Chemistry

Herein, we report a dia-type metal-organic hybrid network based on the [Ag4Br6] clusters and hexamethylenetetramine molecules wherein both the inorganic nodes and organic linkers feature adamantane-like geometry with a Td symmetry. The silver bromine complex presents a dual emission and exhibits an interesting luminescent thermochromism behavior. Remarkably, white-light emission can be readily realized through variation of the temperature. In addition, the title compound is expected to be competent as a luminescent thermometer for temperature identification.

Luminescent Thermochromism and White-Light Emission of a 3D [Ag4Br6] Cluster-Based Coordination Framework with Both Adamantane-like Node and Linker