Luminescent Thermochromism and White-Light Emission of a 3D [Ag₄Br₆] Cluster-Based Coordination Framework with Both Adamantane-like Node and Linker

Herein, we report a dia-type metal–organic hybrid network based on the [Ag4Br6] clusters and hexamethylenetetramine molecules wherein both the inorganic nodes and organic linkers feature adamantane-like geometry with a Td symmetry. The silver bromine complex presents a dual emission and exhibits an interesting luminescent thermochromism behavior. Remarkably, white-light emission can be readily realized through variation of the temperature. In...