Original paper
Catalytic Asymmetric Homologation of Ketones with α-Alkyl α-Diazo Esters
Volume: 143, Issue: 5, Pages: 2394 - 2402
Published: Jan 28, 2021
Abstract
The homologation of ketones with diazo compounds is a useful strategy to synthesize one-carbon chain-extended acyclic ketones or ring-expanded cyclic ketones. However, the asymmetric homologation of acyclic ketones with α-diazo esters remains a challenge due to the lower reactivity and complicated selectivity. Herein, we report the enantioselective catalytic homologation of acetophenone and related derivatives with α-alkyl α-diazo esters...
Paper Details
Title
Catalytic Asymmetric Homologation of Ketones with α-Alkyl α-Diazo Esters
Published Date
Jan 28, 2021
Volume
143
Issue
5
Pages
2394 - 2402
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