Original paper
Revision of the Structure of Hypatulone A by NMR, Computations, and Biosynthetic Considerations
Abstract
Recently, a paper in this journal reported the isolation and structure determination of hypatulone A. Several features of the proposed structure and biosynthesis induced us to reexamine the compound’s NMR spectra. Now we propose a revised structure, confirm it with quantum computations, and suggest a reasonable radical-mediated biosynthetic pathway to the revised structure. Our work illustrates how both biosynthetic considerations and quantum...
Paper Details
Title
Revision of the Structure of Hypatulone A by NMR, Computations, and Biosynthetic Considerations
Published Date
Jan 7, 2020
Journal
Volume
22
Issue
2
Pages
760 - 763
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Notes
History