σ-H–H, σ-C–H, and σ-Si–H Bond Activation Catalyzed by Metal Nanoparticles

Volume: 120, Issue: 2, Pages: 1042 - 1084
Published: Oct 29, 2019
Abstract
Activation of H-H, Si-H, and C-H bonds through σ-bond coordination has grown in the past 30 years from a scientific curiosity to an important tool in the functionalization of hydrocarbons. Several mechanisms were discovered via which the initially σ-bonded substrate could be converted: oxidative addition, heterolytic cleavage, σ-bond metathesis, electrophilic attack, etc. The use of metal nanoparticles (NPs) in this area is a more recent...
Paper Details
Title
σ-H–H, σ-C–H, and σ-Si–H Bond Activation Catalyzed by Metal Nanoparticles
Published Date
Oct 29, 2019
Volume
120
Issue
2
Pages
1042 - 1084
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