Electrical engineering

Physics

Channel (broadcasting)

Engineering

Interferometry

Superposition principle

Quantum dissipation

Interference (communication)

Quantum mechanics

Matter wave

Quantum superposition

Classical mechanics

Quantum phases

Quantum

Nature Physics

Matter-wave interference experiments provide a direct confirmation of the quantum superposition principle, a hallmark of quantum theory, and thereby constrain possible modifications to quantum mechanics1. By increasing the mass of the interfering particles and the macroscopicity of the superposition2, more stringent bounds can be placed on modified quantum theories such as objective collapse models3. Here, we report interference of a molecular library of functionalized oligoporphyrins4 with masses beyond 25,000 Da and consisting of up to 2,000 atoms, by far the heaviest objects shown to exhibit matter-wave interference to date. We demonstrate quantum superposition of these massive particles by measuring interference fringes in a new 2-m-long Talbot–Lau interferometer that permits access to a wide range of particle masses with a large variety of internal states. The molecules in our study have de Broglie wavelengths down to 53 fm, five orders of magnitude smaller than the diameter of the molecules themselves. Our results show excellent agreement with quantum theory and cannot be explained classically. The interference fringes reach more than 90% of the expected visibility and the resulting macroscopicity value of 14.1 represents an order of magnitude increase over previous experiments2. Matter-wave interference experiments demonstrate quantum superposition of molecules consisting of up to 2,000 atoms—the heaviest objects to show this quantum behaviour to date. This provides a bound on potential modifications to quantum mechanics.

Quantum superposition of molecules beyond 25 kDa