Enzymatic poly(gallic acid): A stable multiradical polyanion
Abstract
In this work we re-examined the molecular structure of enzymatic poly(gallic acid) (PGAL), for which we identified a multiradical and polyanionic nature, in contrast to a previous assignment where it was mistakenly assumed as a neutral and diamagnetic molecule. Here, we present a profound investigation of its ground-state structure by the use of both experimental and theoretical methods, featuring ESR measurements and quantum chemical...
Paper Details
Title
Enzymatic poly(gallic acid): A stable multiradical polyanion
Published Date
Dec 1, 2019
Volume
1197
Pages
326 - 335
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