Bi‐Microporous Metal–Organic Frameworks with Cubane [M₄(OH)₄] (M=Ni, Co) Clusters and Pore‐Space Partition for Electrocatalytic Methanol Oxidation Reaction

Embedding cubane [M 4 (OH) 4 ] (M=Ni, Co) clusters within the matrix of metal–organic frameworks (MOFs) is a strategy to develop materials with unprecedented synergistic properties. Herein, a new material type based on the pore‐space partition of the cubic primitive minimal‐surface net (MOF‐14‐type) has been realized. CTGU‐15 made from the [Ni 4 (OH) 4 ] cluster not only has very high BET surface area (3537 m 2 g −1 ), but also exhibits...