Catalytic Enantioselective Intermolecular Benzylic C(sp 3 )−H Amination
Volume: 58, Issue: 24, Pages: 8192 - 8196
Published: May 8, 2019
Abstract
A practical general method for asymmetric intermolecular benzylic C(sp 3 )−H amination has been developed by combining the pentafluorobenzyl sulfamate PfbsNH 2 with the chiral rhodium(II) catalyst Rh 2 (S‐tfptad) 4 . Various substrates can be used as limiting components and converted to benzylic amines with excellent yields and high levels of enantioselectivity. Additional key features for the reaction are the low catalyst loading and the...
Paper Details
Title
Catalytic Enantioselective Intermolecular Benzylic C(sp 3 )−H Amination
Published Date
May 8, 2019
Volume
58
Issue
24
Pages
8192 - 8196
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