Simultaneous Trapping of C₂H₂ and C₂H₆ from a Ternary Mixture of C₂H₂/C₂H₄/C₂H₆ in a Robust Metal–Organic Framework for the Purification of C₂H₄

The removal of C 2 H 2 and C 2 H 6 from C 2 H 4 streams is of great significance for feedstock purification to produce polyethylene and other commodity chemicals but the simultaneous adsorption of C 2 H 6 and C 2 H 2 over C 2 H 4 from a ternary mixture has never been realized. Herein, a robust metal–organic framework, TJT‐100, was designed and synthesized, which demonstrates remarkably selective adsorption of C 2 H 2 and C 2 H 6 over C 2 H 4 ....