Original paper

Highly Regio- and Stereoselective Catalytic Synthesis of Conjugated Dienes and Polyenes

Volume: 140, Issue: 27, Pages: 8434 - 8438
Published: Jun 24, 2018
Abstract
Conjugated dienes and polyenes are typically synthesized by sequential introduction of C═C bonds. Here, we report a practical and scalable, catalytic dienylation that is highly regio- and stereoselective for both C═C bonds. The reaction is enabled by a stereoselective palladium-catalyzed cross-coupling that is preceded by a regioselective base-induced ring opening of readily available sulfolenes. The dienylation reaction is particularly useful...
Paper Details
Title
Highly Regio- and Stereoselective Catalytic Synthesis of Conjugated Dienes and Polyenes
Published Date
Jun 24, 2018
Volume
140
Issue
27
Pages
8434 - 8438
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