Thioimidazolium Ionic Liquids as Tunable Alkylating Agents
Abstract
Alkylating ionic liquids based on the thioimidazolium structure combine the conventional properties of ionic liquids, including low melting point and nonvolatility, with the alkylating function. Alkyl transfer occurs exclusively from the S-alkyl position, thus allowing for easy derivatization of the structure without compromising specificity. We apply this feature to tune the electrophilicty of the cation to profoundly affect the reactivity of...
Paper Details
Title
Thioimidazolium Ionic Liquids as Tunable Alkylating Agents
Published Date
Jan 2, 2018
Volume
83
Issue
2
Pages
684 - 689
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