Asymmetric Hybrid Polymer–Lipid Giant Vesicles as Cell Membrane Mimics

Lipid membrane asymmetry plays an important role in cell function and activity, being for instance a relevant signal of its integrity. The development of artificial asymmetric membranes thus represents a key challenge. In this context, an emulsion‐centrifugation method is developed to prepare giant vesicles with an asymmetric membrane composed of an inner monolayer of poly(butadiene)‐ b ‐poly(ethylene oxide) (PBut‐ b ‐PEO) and outer monolayer of...