Original paper
Sulfur-mediated C(sp 2 )–H imidation and 1,2-imidofluorination of vinyl sulfides
Abstract
A new strategy for the C(sp2)–H imidation and 1,2-imidofluorination of vinylsulfides has been established through simple treatment with N-fluorobis(benzenesulfonyl)imide, which acts as both oxidant and nitrogen source. For alkyl and electron-rich aryl vinylsulfides, alkyl/arylthioenamines are produced in up to 92% total yields. However, for steric and electron-deficient aryl vinylsulfides, 1,2-imidofluorination products are prepared in up to 73%...
Paper Details
Title
Sulfur-mediated C(sp 2 )–H imidation and 1,2-imidofluorination of vinyl sulfides
Published Date
Jun 1, 2017
Journal
Volume
73
Issue
24
Pages
3338 - 3346
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Notes
History