In Situ Two-Phase Ligand Exchange: A New Method for the Synthesis of Alloy Nanoclusters with Precise Atomic Structures

Volume: 139, Issue: 16, Pages: 5668 - 5671
Published: Apr 12, 2017
Abstract
A new method termed “in situ two-phase ligand exchange” was developed to obtain alloy nanoclusters. With this approach, a series of alloy nanoclusters were obtained for the first time, including Au20Ag1(SR)15, Au21–xAgx(SR)15 (x = 4–8), Au21–xCux(SR)15 (x = 0, 1), and Au21–xCux(SR)15 (x = 2–5) (R = tert-butyl). Interestingly, single-crystal X-ray crystallography (SC-XRD) shows that their frameworks are all alike except for Au21–xCux(SR)15 (x =...
Paper Details
Title
In Situ Two-Phase Ligand Exchange: A New Method for the Synthesis of Alloy Nanoclusters with Precise Atomic Structures
Published Date
Apr 12, 2017
Volume
139
Issue
16
Pages
5668 - 5671
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