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Original paper

Dynamical importance of van der Waals saddle and excited potential surface in C(1D)+D2 complex-forming reaction

Volume: 8, Issue: 1
Published: Jan 17, 2017
Abstract
Encouraged by recent advances in revealing significant effects of van der Waals wells on reaction dynamics, many people assume that van der Waals wells are inevitable in chemical reactions. Here we find that the weak long-range forces cause van der Waals saddles in the prototypical C( 1 D )+D 2 complex-forming reaction that have very different dynamical effects from van der Waals wells at low collision energies. Accurate quantum dynamics...
Paper Details
Title
Dynamical importance of van der Waals saddle and excited potential surface in C(1D)+D2 complex-forming reaction
Published Date
Jan 17, 2017
Volume
8
Issue
1
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