Rational Synthesis and Investigation of Porous Metal–Organic Framework Materials from a Preorganized Heterometallic Carboxylate Building Block
Abstract
The tetranuclear heterometallic complex [Li2Zn2(piv)6(py)2] (1, where piv– = pivalate and py = pyridine) has been successfully employed as a presynthesized node for the construction of four porous metal–organic frameworks (MOFs) [Li2Zn2(R-bdc)3(bpy)]·solv (2-R, R-bdc2–; R = H, Br, NH2, NO2) by reaction with 4,4′-bipyridine (bpy) and terephthalate anionic linkers. The [Li2Zn2] node is retained in the products, representing a rare example of the...
Paper Details
Title
Rational Synthesis and Investigation of Porous Metal–Organic Framework Materials from a Preorganized Heterometallic Carboxylate Building Block
Published Date
Jan 10, 2017
Journal
Volume
56
Issue
3
Pages
1599 - 1608
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