New reactivity of 6,6-bis-donor-substituted pentafulvenes: one-step synthesis of highly substituted [3]cumulene and dihydropentalene
Abstract
We report the preparation of a 6,6-bis[(4-N,N-dimethylanilino)ethynyl]pentafulvene from a 6,6-dibromopentafulvene and 4-ethynyl-N,N-dimethylaniline under Sonogashira cross-coupling conditions. A push–pull [3]cumulene was formed unexpectedly during this reaction in moderate yield. The 6,6-bis[(4-N,N-dimethylanilino)ethynyl]pentafulvene was reacted with tetracyanoethylene, and an unprecedented 1,2-dihydropentalene was obtained in high yield as the...
Paper Details
Title
New reactivity of 6,6-bis-donor-substituted pentafulvenes: one-step synthesis of highly substituted [3]cumulene and dihydropentalene
Published Date
Jun 1, 2015
Journal
Volume
71
Issue
25
Pages
4393 - 4399
Citation AnalysisPro
You’ll need to upgrade your plan to Pro
Looking to understand the true influence of a researcher’s work across journals & affiliations?
- Scinapse’s Top 10 Citation Journals & Affiliations graph reveals the quality and authenticity of citations received by a paper.
- Discover whether citations have been inflated due to self-citations, or if citations include institutional bias.
Notes
History