General principles of pharmaceutical solid polymorphism A supramolecular perspective
Abstract
The diversity of solid-state forms that an active pharmaceutical ingredient (API) may attain relies on the repertoire of non-covalent interactions and molecular assemblies, the range of order, and the balance between entropy and enthalpy that defines the free energy landscape. It is recognized that crystallization is associated with molecular recognition events that lead to self-assembly, and that pharmaceutical function and thermodynamic...
Paper Details
Title
General principles of pharmaceutical solid polymorphism A supramolecular perspective
Published Date
Feb 23, 2004
Volume
56
Issue
3
Pages
241 - 274
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