Review paper
Photoredox Activation for the Direct -Arylation of Ketones and Aldehydes
Abstract
The direct β-activation of saturated aldehydes and ketones has long been an elusive transformation. We found that photoredox catalysis in combination with organocatalysis can lead to the transient generation of 5π-electron β-enaminyl radicals from ketones and aldehydes that rapidly couple with cyano-substituted aryl rings at the carbonyl β-position. This mode of activation is suitable for a broad range of carbonyl β-functionalization reactions...
Paper Details
Title
Photoredox Activation for the Direct -Arylation of Ketones and Aldehydes
Published Date
Mar 29, 2013
Journal
Volume
339
Issue
6127
Pages
1593 - 1596
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