Selectivity

Organic chemistry

Hydroxymethyl

Photocatalysis

Radical

Catalysis

Chemistry

Aldehyde

5-hydroxymethylfurfural

Oxygen

Photochemistry

Angewandte Chemie International Edition

Owing to the easy over‐oxidation, it is a promising yet challenging task to explore renewable carbon resources to control the sunlight‐driven selective catalytic oxidation of biomass‐derived 5‐hydroxymethylfurfural (HMF), producing important chemical feedstocks, namely, less‐oxidized 2,5‐diformylfuran (DFF) and 5‐hydroxymethyl‐2‐furancarboxylic acid (HMFCA). Herein, we have developed a photocatalyst by anchoring a Ru complex on CdS quantum dots, which achieves selective oxidation of HMF toward DFF or HMFCA with high conversion (&gt;81 %) and selectivity (&gt;90 %), based on the controllable generation of two oxygen radicals under different atmospheres. Such selective conversion can also work well outside the laboratory by using natural sunlight. In particular, the selective production of HMFCA through photocatalytic HMF oxidation is achieved for the first time. More importantly, our photocatalyst is applicable for the selective oxidation of other compounds with hydroxyl and aldehyde groups.

Sunlight‐Driven Highly Selective Catalytic Oxidation of 5‐Hydroxymethylfurfural Towards Tunable Products