Post‐assembly modification of discrete poly‐NHC‐derived organometallic assemblies

The post‐assembly modification (PAM) of metallosupramolecular assemblies plays an important role in obtaining diverse architectures and expanding new functions. In this work, the trinuclear organometallic assemblies [Ag 3 ( L ) 2 ](PF 6 ) 3 ( L = 1a – c ) were generated from the corresponding internal olefin‐bridged trisimidazolium, trisbenzoimidazolium, and trisimidazo[1,5‐ ɑ ]pyridinium salts H 3 ‐ L (PF 6 ) 3 ( L = 1a – c ) with Ag 2 O...