Construction of novel hexanuclear Co(II) and dinuclear Ni(II) bis(salamo)‐type complexes

Two novel homomultinuclear complexes [Co 6 (L) 2 ( μ ‐OAc) 4 ]·2CHCl 3 ·CH 3 COCH 3 ( 1 ) and [Ni 2 (L)(H 2 O) 2 (Py) 2 ]·2CHCl 3 ( 2 ) with a newly designed rigid bis(salamo)‐type tetraoxime ligand (H 4 L) were synthesized and characterized by elemental analyses, Fourier transform infrared (FT‐IR) spectra, UV–Vis absorption spectra, and X‐ray single‐crystal diffractions. Complex 1 is a novel triple‐decker symmetrical six‐core cluster structure...