Spontaneous N2 formation by a diruthenium complex enables electrocatalytic and aerobic oxidation of ammonia

The electrochemical conversion of ammonia to dinitrogen in a direct ammonia fuel cell (DAFC) is a necessary technology for the realization of a nitrogen economy. Previous efforts to catalyse this reaction with molecular complexes required the addition of exogenous oxidizing reagents or application of potentials greater than the thermodynamic potential for the oxygen reduction reaction-the cathodic process of a DAFC. We report a stable...