Long Wavelength Thermal Density Fluctuations in Molecular and Polymer Glass-Forming Liquids: Experimental and Theoretical Analysis under Isobaric Conditions

We establish via an in-depth analysis of experimental data that the dimensionless compressibility (proportional to the dimensionless amplitude of long wavelength thermal density fluctuations) of one-component normal and supercooled liquids of chemically complex nonpolar and weakly polar molecules and polymers follows extremely well a surprisingly simple and general temperature dependence over an exceptionally wide range of pressures and...