Tailoring a new oxyhydride, CaVO3-H , with ordered hydride anions
Abstract
A new oxyhydride CaVO3-xHx with ordered hydride anions was synthesized by topochemical reaction between hydrogen gas and oxygen-deficient perovskite, CaVO3-δ with ordered oxygen vacancies. The existence of hydride anions was confirmed by 1H nuclear magnetic resonance (NMR) measurements. Hydride anions occupy the oxygen vacancy sites of CaVO3-δ, forming VO4H2 octahedra with cis-geometry and a four-row chain made of cis-VO4H2 octahedra running...
Paper Details
Title
Tailoring a new oxyhydride, CaVO3-H , with ordered hydride anions
Published Date
Jan 1, 2022
Volume
305
Pages
122685 - 122685
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