TEMPO-radical-bearing metal–organic frameworks and covalent organic frameworks for catalytic applications

It is known that 2,2,6,6-tetramethylpiperidinyl-1-oxy (or TEMPO) is a stable, radical-containing molecule, which has been utilized in various areas of organic synthesis, catalysis, polymer chemistry, electrochemical reactions, and materials chemistry. Its unique stability, attributable to its structural features, and molecular tunability allows for the modification of various materials, including the heterogenization of solid materials....