A Catalyst/Oxidant/Base Free Benzylic Csp³−H Alkoxylation of toluidines via Electro‐oxidative Csp³−O‐Coupling with Alcohols

Functionalization of Csp 3 −H bond meets various challenges owing to their well‐known inertness. The task becomes even more challenging for carbon‐heteroatom coupling e. g., Csp 3 −O coupling. Herein we report an electrochemical approach for the direct regioselctive cross‐dehydrogenative hetero‐coupling of benzylic Csp 3 −H bonds of toluidines with alcohols at room temperature under external catalyst, oxidant and base‐free condition. The...