Metal‐to‐Metal Distance Modulation by Ligand Design: A Case Study of Structure‐Property Correlation in Planar Chiral Cyclophanyl Metal Complexes

Multinuclear metal complexes have seen tremendous progress in synthetic advances, their versatile structural features, and emerging applications. Here, we conceptualize Metal-to-Metal distance modulation in cyclophanyl metal complexes by bridging ligand design employing the co-facially stacked cyclophanyl-derived pseudo-geminal, -ortho, -meta, and -para constitutional isomers grafted with N-, O-, and P- containing chelates that allow the...