framework mof

photocatalytic degradation

photocatalytic activity

bi wo

methylene blue

conjugated microporous

degradation methylene

Journal of Molecular Liquids

• D-Fe-MOFs was prepared by DBD plasma for the first time. • D-Fe-MOFs had better photocatalytic degradation performance than S-Fe-MOFs. • Fe-O clusters inhibited the recombination of photo-generated carriers. • ·O 2 – , ·OH and photo-generated holes (h + ) played important roles in photocatalysis. A novel dual-ligand Fe-based MOFs (D-Fe-MOFs) was synthesized with dielectric barrier discharge (DBD) plasma for the first time, which exhibited efficient simulated solar light photocatalytic performance. 1,3,5-Benzenetricarboxylicacid (H 3 BTC) and 2-methylimidazole (2MI) were used as organic ligands for D-Fe-MOFs synthesis. Compared with S-Fe-MOFs, which used H 3 BTC as organic ligand, D-Fe-MOFs showed larger specific surface area and larger pore volume. The molar ratio of different organic ligands had a great influence on the photocatalytic performance of the catalyst, and H 3 BTC:2MI = 1:1 was the most beneficial to the photocatalytic performance. D-Fe-MOFs synthesized under the conditions of discharge voltage 15.6 kV, discharge current 1.5A and discharge time 1.5 h had higher thermal stability and showed high photocatalytic performance with degradation rate of 97% in 48 min for MO (20 mg/L) under simulated solar light. D-Fe-MOFs synthesized with DBD plasma exhibited sufficient conduction and valence band positions, which was beneficial for photocatalysis, where ·O 2 – , ·OH and h + played important roles.

A novel dual-ligand Fe-based MOFs synthesized with dielectric barrier discharge (DBD) plasma as efficient photocatalysts