Brittle-to-Ductile Transition of Sulfonated Polystyrene Ionomers

This study examines the brittle-to-ductile transition of sulfonated polystyrene ionomers (SPS) with different counterions. The polystyrene precursor was unentangled and had two ionic groups per chain on average. Thus, its terminal relaxation time was comparable to the lifetime of the associating ionic groups. Three types of ionomer samples were used to tune the association lifetime: (1) fully neutralized SPS with different alkali-metal...