Nickel-Catalyzed 1,2-Carboamination of Alkenyl Alcohols

Volume: 143, Issue: 34, Pages: 13962 - 13970
Published: Aug 20, 2021
Abstract
An alcohol-directed, nickel-catalyzed three-component umpolung carboamination of unactivated alkenes with aryl/alkenylboronic esters and electrophilic aminating reagents is reported. This transformation is enabled by specifically tailored O-(2,6-dimethoxybenzoyl)hydroxylamine electrophiles that suppress competitive processes, including undesired β-hydride elimination and transesterification between the alcohol substrate and electrophile. The...
Paper Details
Title
Nickel-Catalyzed 1,2-Carboamination of Alkenyl Alcohols
Published Date
Aug 20, 2021
Volume
143
Issue
34
Pages
13962 - 13970
Citation AnalysisPro
  • Scinapse’s Top 10 Citation Journals & Affiliations graph reveals the quality and authenticity of citations received by a paper.
  • Discover whether citations have been inflated due to self-citations, or if citations include institutional bias.