Catalyst-controlled enantioselective 1,1-arylboration of unactivated olefins

Volume: 3, Issue: 11, Pages: 951 - 958
Published: Oct 19, 2020
Abstract
Enantioselective difunctionalization of alkenes constitutes an efficient strategy to assemble complex chiral molecules from simple racemic or achiral starting materials. Here we present an intermolecular nickel-catalysed enantioselective 1,1-arylboration of unactivated terminal alkenes. The high regio- and enantioselectivities of the reactions arise from a judicious choice of the nickel catalyst rather than the incorporation of a directing...
Paper Details
Title
Catalyst-controlled enantioselective 1,1-arylboration of unactivated olefins
Published Date
Oct 19, 2020
Volume
3
Issue
11
Pages
951 - 958
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