FhuA–Grubbs–Hoveyda Biohybrid Catalyst Embedded in a Polymer Film Enables Catalysis in Neat Substrates

Incorporation of metal catalysts into protein scaffolds results in biohybrid catalysts, which have been shown to catalyze various non-natural reactions. Until recently, catalysis with biohybrid catalysts has been performed exclusively in aqueous solutions to maintain the structural integrity of protein scaffolds. Here, we present the incorporation of a biohybrid catalyst into a synthetic polymer film. Ferric hydroxamate uptake protein component...