Original paper
Probing surface structure on two-dimensional metal-organic layers to understand suppressed interlayer packing
Abstract
Two-dimensional metal-organic layers (MOLs) from alternatively connected benzene-tribenzoate ligands and Zr6(μ3-O)4(μ3-OH)4 or Hf6(μ3-O)4(μ3-OH)4 secondary building units can be prepared in gram scale via solvothermal synthesis. However, the reason why the monolayers did not pack to form thick crystals is unknown. Here we investigated the surface structure of the MOLs by a combination of sum-frequency generation spectroscopy, nanoscale infrared...
Paper Details
Title
Probing surface structure on two-dimensional metal-organic layers to understand suppressed interlayer packing
Published Date
Aug 25, 2020
Journal
Volume
13
Issue
11
Pages
3151 - 3156
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Notes
History