Ionic‐Conducting and Robust Multilayered Solid Electrolyte Interphases for Greatly Improved Rate and Cycling Capabilities of Sodium Ion Full Cells

The energy storage performance of sodium‐ion batteries has been greatly improved by pairing ether‐based electrolytes with high‐capacity alloy‐type anodes. However, the origin of this performance improvement by a unique electrode/electrolyte interface has yet to be explored. To understand such results, herein, the deterministic and distinct interfacial chemistries and solid electrolyte interphase (SEI) layers in both the ether‐ and ester‐based...