Volumetric and ultrasonic studies of molecular interactions of glycols in aqueous glutaraldehyde solutions at different temperatures

Published on Oct 1, 2020in Journal of Molecular Liquids5.065
· DOI :10.1016/J.MOLLIQ.2020.113763
Parminder Kaur4
Estimated H-index: 4
(LPU: Lovely Professional University),
Parminder Kaur1
Estimated H-index: 1
(LPU: Lovely Professional University)
+ 1 AuthorsHarsh Kumar23
Estimated H-index: 23
(NITJ: Dr. B. R. Ambedkar National Institute of Technology Jalandhar)
Source
Abstract
Abstract In the current work, Density and speed of sound (ultrasonic speed) of liquid mixtures of (ethylene, diethylene and triethylene glycols + aqueous glutaraldehyde solutions) have been investigated at the temperature ranges of (293.15 K, 298.15 K, 303.15 K and 308.15 K) and in the concentration of (0.01, 0.02, 0.03 and 0.04) mol·kg−1. Different thermodynamic and acoustic parameters have also been calculated using density and speed of sound experimental values. Vϕ (apparent molar) and Vϕ0 (partial molar) volumes and ΔVϕ0 (partial molar volume of transfer) have been estimated using experimental values of density. Using speed of sound values, Kϕ, s (apparent molar) and Kϕ, s0 (partial molar) isentropic compressions and ΔKϕ, s0 (partial molar isentropic compression of transfer) have been obtained. Using partial molar volume of transfer and partial molar isentropic compression of transfer values, the pair and triplet interaction coefficients have also been computed. The final outcome of the research is studied in terms of solute-solvent interactions between the molecules of liquid mixtures.
📖 Papers frequently viewed together
11 Citations
5 Citations
2020
3 Authors (Ashima, ..., Harsh Kumar)
3 Citations
References34
Newest
#1Nabaparna Chakraborty (LPU: Lovely Professional University)H-Index: 3
#2Kirandeep Kaur (LPU: Lovely Professional University)H-Index: 7
Last. Harsh Kumar (NITJ: Dr. B. R. Ambedkar National Institute of Technology Jalandhar)H-Index: 23
view all 4 authors...
In order to arbitrate and understand the synergy between the sugar alcohol xylitol and glycols, the volumetric and acoustical parameters are being calculated from the experimental speed of sound and density data at a variation of temperature from 288.18 to 318.15 K, in (0.01, 0.02, and 0.03) mol·kg–1. Volumetric parameters, such as Vϕ, that is, apparent molar volume, and ΔVϕ0, that is, standard partial molar volume of transfer, in the aqueous solutions of xylitol for the glycols have been calcul...
8 CitationsSource
#1Ashima (LPU: Lovely Professional University)H-Index: 2
#2K.C. Juglan (LPU: Lovely Professional University)H-Index: 8
Last. Harsh Kumar (NITJ: Dr. B. R. Ambedkar National Institute of Technology Jalandhar)H-Index: 23
view all 3 authors...
Abstract Volumetric and acoustic analysis is set in motion to inspect the sodium ethylparaben interaction with ethylene glycol, and propylene glycol as a function of temperature. The estimation of apparent molar volume and apparent molar isentropic compression of glycols in aqueous solutions of sodium ethylparaben has been done by employing densities and speed of the sound measurements at p = 0.1 MPa and T = 293.15 to 308.15 K. The partial molar volume, partial molar isentropic compression, part...
3 CitationsSource
#1Ashima (LPU: Lovely Professional University)H-Index: 2
#2K.C. Juglan (LPU: Lovely Professional University)H-Index: 8
Last. Harsh Kumar (NITJ: Dr. B. R. Ambedkar National Institute of Technology Jalandhar)H-Index: 23
view all 3 authors...
Abstract In the current work, the apparent molar properties and partial molar properties have been assessed from the measurement of density and speed of sound with the interest to inspect the interconnection of polyethylene glycols viz. PEG-200 and PEG-600 in aqueous solutions of sodium methylparaben at several temperature varying from 293.15 K to 308.15 K and experimental pressure p = 0.1 MPa. The investigation of apparent molar volume ( V ϕ ), partial molar volume ( V ϕ 0 ) and partial molar v...
5 CitationsSource
#1Ashima Thakur (LPU: Lovely Professional University)H-Index: 1
#2K.C. Juglan (LPU: Lovely Professional University)H-Index: 8
Last. Kirandeep Kaur (LPU: Lovely Professional University)H-Index: 7
view all 4 authors...
Abstract To determine the nature of interaction of ethylene glycol (EG), propylene glycol (PG), and hexylene glycol (HG) in the methanol solutions of methylparaben, density and speed of the sound of ethylene glycol, propylene glycol, and hexylene glycol in methylparaben–methanol (MePB–MeOH) solutions were investigated at different temperatures (from 293.15 to 308.15 K) and at the pressure, p = 0.1 MPa. The computed density and speed of sound values were utilized to determine the apparent molar v...
12 CitationsSource
#1Nabaparna Chakraborty (LPU: Lovely Professional University)H-Index: 3
#2Harsh Kumar (NITJ: Dr. B. R. Ambedkar National Institute of Technology Jalandhar)H-Index: 23
Last. K.C. Juglan (LPU: Lovely Professional University)H-Index: 8
view all 4 authors...
Abstract The interaction of EG, DEG and TEG with biologically active D-Panthenol, as the function of temperature has been investigated by the combination of acoustic and volumetric methods. Speeds of sound and densities of EG, DEG and TEG in (0.05, 0.10 and 0.15) mol·kg−1 in aqueous solutions of D-Panthenol have been measured at T = (293.15, 298.15, 303.15 and 308.15) K. From the density data, the apparent molar volume ( V ϕ 0 ) and standard partial molar volume of transfer Δ V ϕ 0 for EG, DEG a...
18 CitationsSource
#1Kirandeep Kaur (LPU: Lovely Professional University)H-Index: 7
#2K.C. Juglan (LPU: Lovely Professional University)H-Index: 8
Last. Harsh Kumar (NITJ: Dr. B. R. Ambedkar National Institute of Technology Jalandhar)H-Index: 23
view all 3 authors...
Abstract From the measurements of density and speed of sound, the apparent molar properties and the partial molar properties have been determined to study the interactions of two polyethylene glycols i.e. polyethylene glycol 400 and polyethylene glycol 4000 in aqueous solutions of sorbitol at experimental pressure p = 0.1 MPa and temperatures T = (288.15–318.15) K. Evaluation of partial molar volume (Vϕo), apparent molar volume (Vϕ) and partial molar volumes of transfer (ΔVϕo) is done using dens...
15 CitationsSource
#1Kirandeep Kaur (LPU: Lovely Professional University)H-Index: 7
#2Isha Behal (NITJ: Dr. B. R. Ambedkar National Institute of Technology Jalandhar)H-Index: 8
Last. Harsh Kumar (NITJ: Dr. B. R. Ambedkar National Institute of Technology Jalandhar)H-Index: 23
view all 4 authors...
Abstract Densities and ultrasonic speed of ethylene glycol, diethylene glycol and triethylene glycol in (0.00, 0.01, 0.03, 0.05) mol kg−1 aqueous solutions of glycerol have been measured at T = (293.15, 298.15, 303.15, 308.15) K and experimental pressure p = 0.1 MPa. From the density data, the apparent molar volume Vϕ, the partial molar volume V ϕ o and the partial molar volumes of transfer Δ V ϕ o have been calculated for glycols from water to aqueous glycerol solutions. Using ultrasonic speed ...
15 CitationsSource
#1Kirandeep KaurH-Index: 7
#2K.C. JuglanH-Index: 8
Last. Harsh KumarH-Index: 23
view all 3 authors...
In the present study, the combination of volumetric and acoustical studies is used to investigate the interactions of ethylene glycol, diethylene glycol, and triethylene glycol with sorbitol as a function of temperature. Densities and ultrasonic velocities of ethylene, diethylene, and triethylene glycol in (0.00, 0.01, 0.03, 0.05) mol·kg–1 aqueous solutions of sorbitol have been measured at temperatures T = (288.15, 298.15, 308.15, 318.15) K and experimental pressure p = 0.1 MPa. With the help o...
19 CitationsSource
#1Harsh Kumar (NITJ: Dr. B. R. Ambedkar National Institute of Technology Jalandhar)H-Index: 23
#2Kirtanjot Kaur (NITJ: Dr. B. R. Ambedkar National Institute of Technology Jalandhar)H-Index: 10
Last. Meenu Singla (NITJ: Dr. B. R. Ambedkar National Institute of Technology Jalandhar)H-Index: 14
view all 4 authors...
Abstract Densities, ρ , speed of sound, u , for aqueous solutions of alkoxyalkanols like ethylene glycol mono methyl ether (EGMME), ethylene glycol mono ethyl ether (EGMEE) and ethylene glycol mono butyl ether (EGMBE) have been measured in aqueous solutions of surfactant sodium dodecyl sulphate (SDS) at temperatures T = (288.15, 298.15, 308.15 and 318.15) K have been measured. The different parameters such as apparent molar volume, limiting apparent molar volume, transfer volume, partial molar e...
7 CitationsSource
#1Harsh Kumar (NITJ: Dr. B. R. Ambedkar National Institute of Technology Jalandhar)H-Index: 23
#2Isha Behal (NITJ: Dr. B. R. Ambedkar National Institute of Technology Jalandhar)H-Index: 8
Abstract The interactions of the drug chloramphenicol with glycine and its dipeptide i.e. glycylglycine have been investigated in aqueous medium from density (ρ) and speed of sound(c) measurements at T = (288.15, 298.15, 308.15, 318.15) K and experimental pressure p = 0.1 MPa. The apparent molar volume ( V ϕ ), the partial molar volume ( V ϕ o ) and standard partial molar volumes of transfer ( Δ V ϕ o ) for glycine and its dipeptide, from water to aqueous chloramphenicol have been calculated fro...
23 CitationsSource
Cited By4
Newest
#1Nabaparna Chakraborty (LPU: Lovely Professional University)H-Index: 3
#2K.C. Juglan (LPU: Lovely Professional University)H-Index: 8
Last. Harsh Kumar (NITJ: Dr. B. R. Ambedkar National Institute of Technology Jalandhar)H-Index: 23
view all 3 authors...
Abstract null null Acoustic and volumetric parameters for the liquid mixture (water + Biotin + ethylene glycol/diethylene glycol/triethylene glycol) are evaluated at different temperatures (288.15 K, 298.15 K, 308.15 K, and 318.15 K) and constant pressure of 0.1 MPa over the range of biotin concentrations (0.0000, 0.0015, 0.0025, and 0.0035) mol· null null null null null K null g null null null - null 1 null null null null null . The experimental work was carried out by Anton Paar DSA 5000 M, wh...
Source
Abstract null null The current study deals with the analysis of the molecular interactions among the glycols (propylene glycol, PG and hexylene glycol, HG) molecules in (0.000, 0.001, 0.002 and 0.003) mol· null null null null null K null g null null null - null 1 null null null null null null aqueous solutions of biotin at constant experimental pressure 0.1 MPa and temperature range (288.15 K, 298.15 K, 308.15 K and 318.15 K). The speed of sound and the density for the liquid mixtures is measure...
Source
#1Parminder Kaur (LPU: Lovely Professional University)H-Index: 4
#2Nabaparna Chakraborty (LPU: Lovely Professional University)H-Index: 3
Last. Meenu Singla (NITJ: Dr. B. R. Ambedkar National Institute of Technology Jalandhar)H-Index: 14
view all 5 authors...
Abstract null null The experimentally obtained density (ρ) and sound velocity (c) values of chlorhexidine (methanol solution) at a concentration of (0.0015, 0.0035 and 0.0055) null null null null m null o null l null ∙ null null null k null g null null null - null 1 null null null null null null with propylene and hexylene glycols at the temperature of 288.15, 298.15, 308.15 and 318 K have been used to calculate the various physico-chemical properties. Apparent molar volume ( null null null null...
Source
#1Diksha Chawla (LPU: Lovely Professional University)
#2Nabaparna Chakraborty (LPU: Lovely Professional University)H-Index: 3
Last. Harsh Kumar (NITJ: Dr. B. R. Ambedkar National Institute of Technology Jalandhar)H-Index: 2
view all 4 authors...
The interlinkage of ethylene glycol, diethylene glycol and triethylene glycol with d-mannitol at different values of temperature has been analysed by the combination of volumetric and acoustic process. Different values of speed of sound and the density of EG, DEG and TEG in the molalities of (0.01, 0.03 and 0.05) mol kg−1 in aqueous solutions of d-mannitol at T = (293.15, 298.15, 303.15 and 308.15) K have been considered. From the values of speed of sound, the partial molar isentropic compressio...
3 CitationsSource