Facile Synthesis and Study of Microporous Catalytic Arene-Norbornene Annulation–Tröger’s Base Ladder Polymers for Membrane Air Separation

Volume: 9, Issue: 5, Pages: 680 - 685
Published: Apr 24, 2020
Abstract
We report the facile synthesis and study of two soluble microporous ladder polymers, CANAL-TBs, by combining catalytic arene-norbornene annulation (CANAL) and Tröger's base (TB) formation. The polymers were synthesized in two steps from commercially available chemicals in high yields. CANAL-TBs easily formed mechanically robust films, were thermally stable up to 440 °C, and exhibited very high Brunauer-Teller-Emmett surface areas of 900-1000 m2...
Paper Details
Title
Facile Synthesis and Study of Microporous Catalytic Arene-Norbornene Annulation–Tröger’s Base Ladder Polymers for Membrane Air Separation
Published Date
Apr 24, 2020
Volume
9
Issue
5
Pages
680 - 685
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