Generation of Halomethyl Radicals by Halogen Atom Abstraction and Their Addition Reactions with Alkenes

Volume: 141, Issue: 42, Pages: 16643 - 16650
Published: Oct 1, 2019
Abstract
α-Aminoradicals undergo halogen atom abstraction to form halomethyl radicals in reactions initiated by the combination of tert-butyl hydroperoxide, aliphatic trialkylamine, halocarbon, and copper(I) iodide. The formation of the α-aminoradical circumvents preferential hydrogen atom transfer in favor of halogen atom transfer, thereby releasing the halomethyl radical for addition to alkenes. The resulting radical addition products add the...
Paper Details
Title
Generation of Halomethyl Radicals by Halogen Atom Abstraction and Their Addition Reactions with Alkenes
Published Date
Oct 1, 2019
Volume
141
Issue
42
Pages
16643 - 16650
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