Phase (matter)

Engineering

Materials science

Layer (electronics)

Crystal structure

Perovskite (structure)

Inorganic chemistry

Chemical engineering

Iodide

Band gap

Nanotechnology

Organic chemistry

Tetragonal crystal system

Crystallography

Chemistry

Energy conversion efficiency

Optoelectronics

Passivation

Science

Tetragonal phases for perovskite solar cells The power conversion efficiencies (PCEs) of all-inorganic perovskites are lower than those of materials with organic cations. This is in part because these materials have larger bandgaps. The cubic crystal phases of these materials also exhibit poor stability. Wang et al. synthesized the tetragonal β-phase of CsPbI 3 from HPbI 3 and CsI. The material exhibited higher stability and a more favorable bandgap, which allowed for PCEs of 15%. Passivation of the surface trap state with choline iodide boosted PCEs to 18%. Science , this issue p. 591

Thermodynamically stabilized β-CsPbI <sub>3</sub> –based perovskite solar cells with efficiencies &gt;18%

Thermodynamically stabilized β-CsPbI 3 –based perovskite solar cells with efficiencies >18%

Thermodynamically stabilized β-CsPbI ₃ –based perovskite solar cells with efficiencies >18%