Original paper

Iron-Catalyzed Aerobic Oxidation of Alcohols: Lower Cost and Improved Selectivity

Volume: 23, Issue: 5, Pages: 825 - 835
Published: Mar 13, 2019
Abstract
An aerobic oxidation reaction of alcohols toward aldehydes or ketones using catalytic amounts of Fe(NO3)3·9H2O, 4-OH-TEMPO, and NaCl has been developed. Compared with the former catalytic system with TEMPO developed in this group, the new protocol using 4-OH-TEMPO, which is much cheaper on an industrial scale, accomplished the transformation with a higher selectivity, especially for aliphatic alcohols toward aldehydes. α,β-Unsaturated alkynals...
Paper Details
Title
Iron-Catalyzed Aerobic Oxidation of Alcohols: Lower Cost and Improved Selectivity
Published Date
Mar 13, 2019
Volume
23
Issue
5
Pages
825 - 835
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