Design and control of gas diffusion process in a nanoporous soft crystal
Abstract
Design of the gas-diffusion process in a porous material is challenging because a contracted pore aperture is a prerequisite, whereas the channel traffic of guest molecules is regulated by the flexible and dynamic motions of nanochannels. Here, we present the rational design of a diffusion-regulatory system in a porous coordination polymer (PCP) in which flip-flop molecular motions within the framework structure provide kinetic gate functions...
Paper Details
Title
Design and control of gas diffusion process in a nanoporous soft crystal
Published Date
Jan 25, 2019
Journal
Volume
363
Issue
6425
Pages
387 - 391
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