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Original paper

Ni-Catalyzed Reductive Liebeskind–Srogl Alkylation of Heterocycles

Volume: 141, Issue: 5, Pages: 1918 - 1922
Published: Jan 16, 2019
Abstract
Herein we present a Ni-catalyzed alkylation of C–SMe with alkyl bromides for the decoration of heterocyclic frameworks. The protocol, reminiscent to the Liebeskind–Srogl coupling, makes use of simple C(sp2)–SMe to be engaged in a reductive coupling. The reaction is suitable for a preponderance of highly valuable heterocyclic motifs. In addition to cyclic bromides, noncyclic alkyl bromides are well accommodated with exquisite levels of retention...
Paper Details
Title
Ni-Catalyzed Reductive Liebeskind–Srogl Alkylation of Heterocycles
Published Date
Jan 16, 2019
Volume
141
Issue
5
Pages
1918 - 1922
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