Analysis and identification of wild and cultivated Paridis Rhizoma by infrared spectroscopy

Published on Aug 5, 2018in Journal of Molecular Structure2.463
· DOI :10.1016/J.MOLSTRUC.2018.03.061
Lan-fen Yang1
Estimated H-index: 1
,
Fang Ma7
Estimated H-index: 7
(THU: Tsinghua University)
+ 1 AuthorsSu-Qin Sun25
Estimated H-index: 25
(THU: Tsinghua University)
Sources
Abstract
Abstract Wild and cultivated Paridis Rhizoma (PR) were analyzed and characterized systematically by integral analysis method and two dimensional correlation infrared spectroscopy, both of which have been successfully utilized in the analysis of complex mixtures. According to their infrared spectra, peaks clusters at around 1642 and 1022 cm−1 could be considered as the key factors to discriminate them. Besides, significant differences emerged in their second derivative spectra, particularly the peaks at 1619, 1317 and 781 cm−1 attributed to calcium oxalate. In addition, standard IR spectra of starch, calcium oxalate and oil were used as references to compare with wild and cultivated PR, indicating that the relative contents of oil in cultivated PR are higher than that in wild PR. While, the relative content of calcium oxalate is higher in wild PR than cultivated one. Moreover, synchronous two-dimensional correlation spectra present great difference in the range of 1750–1350 cm−1. Furtherly, cluster analysis based on principle component analysis algorithm were conducted, obtaining a good classification result.
📖 Papers frequently viewed together
47 Citations
2001
1 Author (Leo Breiman)
34k Citations
13 Citations
References22
Newest
#1Wei Hu (Shanghai Ocean University)H-Index: 6
#2Xiao-Xi Guo (Shanghai Ocean University)H-Index: 5
Last. Yuan Liu (Shanghai Ocean University)H-Index: 25
view all 7 authors...
White croaker surimi, an important raw material of traditional kamaboko industry, commonly has four grades, A, AA, FA, and SA which have distinct quality but are tough to be identified and discriminated rapidly and holistically by conventional methods. A Tri-step infrared spectroscopy, Fourier transform infrared spectroscopy (FT-IR) integrated with second derivative infrared (SD-IR) spectroscopy, and two-dimensional correlation infrared spectroscopy (2DCOS-IR), combined with statistical pattern ...
13 CitationsSource
#1Jianbo Chen (THU: Tsinghua University)H-Index: 16
#2Qun Zhou (THU: Tsinghua University)H-Index: 23
Last. Su-Qin Sun (THU: Tsinghua University)H-Index: 25
view all 3 authors...
Before their medical use, thermal processing methods are frequently utilized to treat the traditional Chinese herbal materials to improve their efficacy or reduce their side effects. Understanding the temperature-dependent chemical reactions of herbal materials is necessary to explore the mechanisms and optimize the procedures of thermal processing. Being a quick, label-free, and nondestructive analytical technique, infrared (IR) spectroscopy can be used to in situ monitor the changes of herbal ...
8 CitationsSource
#1Jianbo Chen (THU: Tsinghua University)H-Index: 16
#2Su-Qin Sun (THU: Tsinghua University)H-Index: 25
Last. Qun Zhou (THU: Tsinghua University)H-Index: 23
view all 3 authors...
The nondestructive and label-free infrared (IR) spectroscopy is a direct tool to characterize the spatial distribution of organic and inorganic compounds in plant. Since plant samples are usually complex mixtures, signal-resolving methods are necessary to find the spectral features of compounds of interest in the signal-overlapped IR spectra. In this research, two approaches using existing data-driven signal-resolving methods are proposed to interpret the IR spectra of plant samples. If the numb...
22 CitationsSource
#1Chang-Hua XuH-Index: 17
#2Jianbo ChenH-Index: 16
Last. Su-Qin SunH-Index: 25
view all 4 authors...
6 CitationsSource
#1Yang Wang (Tianjin University of Traditional Chinese Medicine)H-Index: 8
#2Ping Wang (Tianjin University of Traditional Chinese Medicine)H-Index: 7
Last. Huifen Li (Tianjin Medical University)H-Index: 3
view all 11 authors...
Abstract In this paper, a step-by-step analysis-through-separation method under the navigation of multi-step IR macro-fingerprint (FT-IR integrated with second derivative IR (SD-IR) and 2DCOS-IR) was developed for comprehensively characterizing the hierarchical chemical fingerprints of licorice from entirety to single active components. Subsequently, the chemical profile variation rules of three parts (flavonoids, saponins and saccharides) in the separation process were holistically revealed and...
10 CitationsSource
#1Xian-xue WuH-Index: 1
#2Chang-Hua Xu (Shanghai Ocean University)H-Index: 17
Last. Wei DongH-Index: 1
view all 6 authors...
Abstract Two kinds of reconstituted tobacco (RT) from France (RTF) and China (RTC) were analyzed and identified by a three-level infrared spectroscopy method (Fourier-transform infrared spectroscopy (FT-IR) coupled with second derivative infrared spectroscopy (SD-IR) and two-dimensional infrared correlation spectroscopy (2D-IR)). The conventional IR spectra of RTF parallel samples were more consistent than those of RTC according to their overlapped parallel spectra and IR spectra correlation coe...
12 CitationsSource
#1Jian-Rui Li (CDUTCM: Chengdu University of Traditional Chinese Medicine)H-Index: 2
#2Su-Qin Sun (THU: Tsinghua University)H-Index: 25
Last. Guang-Hua Lu (CDUTCM: Chengdu University of Traditional Chinese Medicine)H-Index: 18
view all 7 authors...
Abstract Five herbs named as Chinese Danggui (CDG), Japanese Danggui (JDG), Korea Danggui (KDG), Lovage root (LR) and Angelica root (AR) are widely and confusedly used in eastern and western countries owing to their homonym. These herbs come from different plant species resulting in the variety of bioactive components and medical efficacy. A method combing tri-step IR macro-fingerprinting techniques with statistical pattern recognition was therefore employed discriminate the five herbs in order ...
31 CitationsSource
#1Xin-Hu Liu (THU: Tsinghua University)H-Index: 1
#2Huan-Jun Xu (SPU: Shenyang Pharmaceutical University)H-Index: 1
Last. Jin-Hui Wang (Shihezi University)H-Index: 1
view all 9 authors...
In this study, two types of Danshen from different growth years were discriminated and identified by a three-step infrared spectroscopy method (Fourier transform-infrared spectroscopy (FT-IR) coupled with second derivative infrared spectroscopy (SD-IR) and two dimensional correlation infrared spectroscopy (2D-IR)). Though only small differences were found in the FT-IR spectra of the samples, the positions and intensities of peaks at around 1635 and 1055 cm−1 could be considered as the key factor...
6 CitationsSource
#1Gaoxue Wang (NWAFU: Northwest A&F University)H-Index: 6
#2Jing Han (NWAFU: Northwest A&F University)H-Index: 3
Last. Xiaolin Liu (NWAFU: Northwest A&F University)H-Index: 24
view all 6 authors...
Abstract The present study was undertaken to investigate the anthelmintic activity of crude extracts and pure compounds from the rhizomes of Paris polyphylla. The methanol extract showed a promising anthelmintic activity against Dactylogyrus intermedius (EC50 value = 18.06 mg l−1). Based on these finding, the methanol extract was fractionated on silica gel column chromatography in a bioassay-guided fractionation affording two known steroidal saponins showing potent activity, dioscin (1) and poly...
104 CitationsSource
#1Suquin Sun (Ministry of Education)H-Index: 1
#2Jianbo ChenH-Index: 16
Last. Kelvin ChanH-Index: 66
view all 5 authors...
Chinese herbal medicines are often referred to as Chinese materia medica (CMM). Composite for- mulae containing mixtures of CMM are pre- scribed for treatment and prevention of diseases in the practice of traditional Chinese medicine (TCM). Some of the well-known CMM formulae (Fufang in Chinese) are manufactured and mar- keted as proprietary Chinese medicines (PCM). Quality assessment and assurance of these prod- ucts are difficult; they are a challenging task. Mid-infrared spectroscopy, a class...
113 CitationsSource
Cited By15
Newest
#1Yan-Li Lü (Heilongjiang University of Chinese Medicine)
#2Jun Liang (Heilongjiang University of Chinese Medicine)H-Index: 12
Last. Yong-Gang Xia (Heilongjiang University of Chinese Medicine)H-Index: 20
view all 5 authors...
Abstract In this study, a novel two-dimensional correlation infrared spectroscopy (2DCOS-IR) is presented to rapidly characterize and discriminate polysaccharides in Panax ginseng (PGP), P. notoginseng (PNP), and P. quinquefolius (PQP) using attenuated total reflection Fourier transform infrared spectroscopy–based on single-characteristic temperature as the external disturbance (2D-sATR-FTIR). Compared with two existing 2DCOS-IR methods based on gradient heating pathways using KBr pellet (100 mi...
Source
#1Hui ChenH-Index: 1
#1Hui ChenH-Index: 11
Last. Hongjin LiH-Index: 2
view all 3 authors...
Abstract Gastrodia elata is a notable medicinal and edible plant. Wild-grown Gastrodia elata is rare in nature and expensive for its medicinal value, which is often the subject of fraudulent practices by replacing them with inexpensive cultivated ones. Developing a rapid and effective method for identifying wild-grown Gastrodia elata is of great importance. The feasibility of combining near-infrared (NIR) spectroscopy with chemometrics for discriminating between wild-grown and cultivated Gastrod...
Source
#1JiaQi Yue (Yunnan University)H-Index: 1
#2Heng-Yu Huang (Yunnan University)H-Index: 2
Last. Yuanzhong WangH-Index: 1
view all 3 authors...
Abstract Spectral analysis has the characteristics of fast and nondestructive. In order to conform to the development of the times, a practical method beyond the traditional spectral analysis was established. For the first time, the two-dimensional correlation spectroscopy (2DCOS) images of Fourier-transform mid-infrared spectroscopy combined with the Residual Neural Network (ResNet) was used for the identification and analysis of 12 Paris species, and the second derivative 2DCOS rarely involved...
1 CitationsSource
#1Wu Haiyun (Tianjin Agricultural University)H-Index: 1
#2Yong Wei (Tianjin Agricultural University)
view all 5 authors...
Abstract To extract the characteristic information of chalk in rice, the chalky milled rice were analyzed systematically by mid-infrared (IR), near-infrared (NIR) spectra analysis and two-dimensional (2D) correlation spectroscopy. 24 non-chalky and 24 chalky rice samples for four types milled rice were prepared in laboratory. NIR diffusing reflection and IR attenuated total reflection (ATR) spectra of all samples were collected at room temperature. The synchronous 2D NIR-NIR correlation spectra ...
Source
#1Yeonju Park (Kangwon National University)H-Index: 14
#2Sila Jin (Kangwon National University)H-Index: 9
Last. Young Mee Jung (Kangwon National University)H-Index: 27
view all 4 authors...
Abstract Noteworthy new progress in 2D correlation spectroscopy (2D-COS) and its versatile applications for the last two years are compiled in this comprehensive survey review. We report the new and significant concepts of 2D-COS, various 2D-COS software and useful display techniques, and numerous applications of 2D-COS in various external perturbations, analytical methods, and systems. Applications of 2D-COS in fluorescence spectroscopy have noticeably increased, as well as applications of 2D-C...
7 CitationsSource
#1Renjie Yang (Tianjin Agricultural University)H-Index: 6
#2Liu Chunyu (Tianjin Agricultural University)H-Index: 1
Last. Liu Haixue (Tianjin Agricultural University)H-Index: 6
view all 7 authors...
Abstract Two-dimensional (2D) correlation between two spectra is called the technology of two-trace two-dimensional (2T2D) correlation spectroscopy by Noda. 2T2D correlation spectroscopy can provide abundant and useful characteristic information of two similar samples, and effectively distinguish the weak difference of two similar spectra. Therefore, it has a good application prospect in identifying similar samples, such as identifying unadulterated and adulterated food. Meanwhile, the quantific...
2 CitationsSource
#1Yun Li (CAS: Chinese Academy of Sciences)H-Index: 5
#1Yun Li (CAS: Chinese Academy of Sciences)H-Index: 1
Last. De-An Guo (CAS: Chinese Academy of Sciences)H-Index: 68
view all 4 authors...
Abstract Herbal medicine (HM) has been playing a pivotal role in maintaining human health since ancient times, and its therapeutic theory and clinical experience are the precious traditional medical knowledge reserves. As HM occupies an important position in its own right in global healthcare systems, robust quality assessment and control over its complex chemical composition was of great significance to assure its efficacy and safety. Over the past decades, the concept of HM chemical fingerprin...
13 CitationsSource
#1Yuhou Zhou (Yunnan University)H-Index: 1
#2Zhi-tian ZuoH-Index: 2
Last. Yuan-zhong WangH-Index: 1
view all 4 authors...
Abstract Traditional Chinese medicine Panax notoginseng is a valuable geo-authentic herbal material. The difference of growth environment in different producing areas has significant influence on the quality of traditional Chinese medicine, and origin identification is an important part of the quality assessment of P. notoginseng. In this study, Fourier transform mid-infrared (FT-MIR) and near infrared (NIR) sensor technologies combined with single spectra analysis and multi-sensor information f...
5 CitationsSource
#1Yi-Fei Pei (Yunnan University)H-Index: 3
#1Yifei Pei (Yunnan University)
Last. Yuanzhong WangH-Index: 19
view all 3 authors...
AbstractGenus Paris mainly distributed in Asia and served as traditional ethnobotanical medicine in China, India, and Nepal. The main aim of this study was to review ethnic minorities medicinal rec...
4 CitationsSource
#1Yi-Fei Pei (Yunnan University)H-Index: 3
#1Yifei Pei (Yunnan University)
Last. Yuan-Zhong WangH-Index: 4
view all 4 authors...
Abstract The rational utilization of aerial parts (stem and leaf) of Paris polyphylla var. yunnanensis ( P. yunnanensis ) is increasingly being studied, due to the growing scarcity of resources. In our study, the geographical origin and cultivation year classification of 662 cultivated P. yunnanensis rhizome, stem and leaf samples from Yuxi, Lijiang and Honghe cities were analyzed by Fourier transform infrared-attenuated total reflectance (FTIR-ATR) spectra using principal component analysis (PC...
2 CitationsSource